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1

Effects of supramolecular architecture on halogen bonding between diiodine and heteroaromatic N-oxides

Nizhnik, Yakov P., Sons, Alex, Zeller, Matthias, Rosokha, Sergiy V.

Journal:

Crystal Growth & Design

Year:

2018

Language:

english

File:

PDF, 1.21 MB

english, 2018

2

π-Bonded molecular wires: self-assembly of mixed-valence cation-radical stacks within the nanochannels formed by inert tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anions

Rosokha, Sergiy V., Stern, Charlotte L., Ritzert, Jeremy T.

Journal:

Year:

2013

Language:

english

File:

PDF, 2.97 MB

english, 2013

3

Halide Recognition through Diagnostic “Anion–π” Interactions: Molecular Complexes of Cl−, Br−, and I− with Olefinic and Aromatic π Receptors

Yaroslav S. Rosokha, Sergey V. Lindeman, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie

Year:

2004

Language:

english

File:

PDF, 142 KB

english, 2004

4

Through-Space (Cofacial) π-Delocalization among Multiple Aromatic Centers: Toroidal Conjugation in Hexaphenylbenzene-like Radical Cations

Duoli Sun, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie

Year:

2005

Language:

english

File:

PDF, 122 KB

english, 2005

5

Halide Recognition through Diagnostic “Anion–π” Interactions: Molecular Complexes of Cl−, Br−, and I− with Olefinic and Aromatic π Receptors

Yaroslav S. Rosokha, Sergey V. Lindeman, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie

Year:

2005

File:

PDF, 34 KB

2005

6

Halide Recognition through Diagnostic “Anion–π” Interactions: Molecular Complexes of Cl−, Br−, and I− with Olefinic and Aromatic π Receptors

Yaroslav S. Rosokha, Sergey V. Lindeman, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie International Edition

Year:

2004

Language:

english

File:

PDF, 142 KB

english, 2004

7

Through-Space (Cofacial) π-Delocalization among Multiple Aromatic Centers: Toroidal Conjugation in Hexaphenylbenzene-like Radical Cations

Duoli Sun, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie International Edition

Year:

2005

Language:

english

File:

PDF, 123 KB

english, 2005

8

Halide Recognition through Diagnostic “Anion–π” Interactions: Molecular Complexes of Cl−, Br−, and I− with Olefinic and Aromatic π Receptors

Yaroslav S. Rosokha, Sergey V. Lindeman, Sergiy V. Rosokha, Jay K. Kochi

Journal:

Angewandte Chemie International Edition

Year:

2005

File:

PDF, 35 KB

2005

9

Charge-Transfer Effects on Arene Structure and Reactivity

Sergiy V. Rosokha, Jay K. Kochi

Journal:

Year:

2004

File:

PDF, 50 KB

2004

10

Spectroscopic and Electrochemical Evaluation of Salt Effects on Electron-Transfer Equilibria between Donor/Acceptor and Ion-Radical Pairs in Organic Solvents

Sergiy V. Rosokha, Duoli Sun, Jeffrey Fisher, Jay K. Kochi

Journal:

Year:

2008

Language:

english

File:

PDF, 437 KB

english, 2008

11

One- and two-dimensional coordination networks of the tetracyanoethylene anion-radicals with potassium counter-ions

Sergiy V. Rosokha, Bernd Lorenz, Tetyana Y. Rosokha, Jay K. Kochi

Journal:

Year:

2009

Language:

english

File:

PDF, 337 KB

english, 2009

12

Intermolecular π-dimer of oxoverdazyl radicals with long-distance multicenter (2e/8c) bonding via nitrogen atoms

Sergiy V. Rosokha, Jing Zhang, Jianjiang Lu, Jay K. Kochi

Journal:

Journal of Physical Organic Chemistry

Year:

2010

Language:

english

File:

PDF, 289 KB

english, 2010

13

Substituent-Induced Switch of the Role of Charge-Transfer Complexes in the Diels–Alder Reactions of o -Chloranil and Styrenes

Rosokha, Sergiy V., Korotchenko, Vasiliy, Stern, Charlotte L., Zaitsev, Vladimir, Ritzert, Jeremy T.

Journal:

Journal of Organic Chemistry

Year:

2012

Language:

english

File:

PDF, 1.51 MB

english, 2012

14

Hybrid Network Formation via Halogen Bonding of the Neutral Bromo-Substituted Organic Molecules with Anionic Metal–Bromide Complexes

Rosokha, Sergiy V, Vinakos, Michael K.

Journal:

Crystal Growth & Design

Year:

2012

Language:

english

File:

PDF, 2.71 MB

english, 2012

15

Novel Arene Receptors as Nitric Oxide (NO) Sensors

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2002

Language:

english

File:

PDF, 47 KB

english, 2002

16

Fresh Look at Electron-Transfer Mechanisms via the Donor/Acceptor Bindings in the Critical Encounter Complex

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Accounts of Chemical Research

Year:

2008

Language:

english

File:

PDF, 493 KB

english, 2008

17

Charge-Transfer Mechanism for Electrophilic Aromatic Nitration and Nitrosation via the Convergence of (ab Initio) Molecular-Orbital and Marcus−Hush Theories with Experiments

Gwaltney, Steven R., Rosokha, Sergiy V., Head-Gordon, Martin, Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 223 KB

english, 2003

18

The Preorganization Step in Organic Reaction Mechanisms. Charge-Transfer Complexes as Precursors to Electrophilic Aromatic Substitutions

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 171 KB

english, 2002

19

Quinones as Electron Acceptors. X-Ray Structures, Spectral (EPR, UV−vis) Characteristics and Electron-Transfer Reactivities of Their Reduced Anion Radicals as Separated vs Contact Ion Pairs

Lü, Jian-Ming, Rosokha, Sergiy V., Neretin, Ivan S., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2006

Language:

english

File:

PDF, 419 KB

english, 2006

20

Donor−Acceptor (Electronic) Coupling in the Precursor Complex to Organic Electron Transfer: Intermolecular and Intramolecular Self-Exchange between Phenothiazine Redox Centers

Sun, Duoli, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2004

Language:

english

File:

PDF, 493 KB

english, 2004

21

Molecular and Electronic Structures of the Long-Bonded π-Dimers of Tetrathiafulvalene Cation-Radical in Intermolecular Electron Transfer and in (Solid-State) Conductivity

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2007

Language:

english

File:

PDF, 223 KB

english, 2007

22

Intermolecular π-to-π Bonding between Stacked Aromatic Dyads. Experimental and Theoretical Binding Energies and Near-IR Optical Transitions for Phenalenyl Radical/Radical versus Radical/Cation Dimerizations

Small, David, Zaitsev, Vladimir, Jung, Yousung, Rosokha, Sergiy V., Head-Gordon, Martin, Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2004

Language:

english

File:

PDF, 241 KB

english, 2004

23

X-ray Structure Analysis and the Intervalent Electron Transfer in Organic Mixed-Valence Crystals with Bridged Aromatic Cation Radicals

Lindeman, Sergey V., Rosokha, Sergiy V., Sun, Duoli, Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2002

Language:

english

File:

PDF, 197 KB

english, 2002

24

Experimental and Computational Probes of the Nature of Halogen Bonding: Complexes of Bromine-Containing Molecules with Bromide Anions

Rosokha, Sergiy V., Stern, Charlotte L., Ritzert, Jeremy T.

Journal:

Chemistry - A European Journal

Year:

2013

Language:

english

File:

PDF, 1.38 MB

english, 2013

25

The Spectral Elucidation versus the X-ray Structure of the Critical Precursor Complex in Bimolecular Electron Transfers: Application of Experimental/Theoretical Solvent Probes to Ion-Radical (Redox) Dyads

Rosokha, Sergiy V., Newton, Marshall D., Jalilov, Almaz S., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2008

Language:

english

File:

PDF, 252 KB

english, 2008

26

Isolation of the Latent Precursor Complex in Electron-Transfer Dynamics. Intermolecular Association and Self-Exchange with Acceptor Anion Radicals

Ganesan, Vellaichamy, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 220 KB

english, 2003

27

Continuum of Outer- and Inner-Sphere Mechanisms for Organic Electron Transfer. Steric Modulation of the Precursor Complex in Paramagnetic (Ion-Radical) Self-Exchanges

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2007

Language:

english

File:

PDF, 353 KB

english, 2007

28

Very Fast Electron Migrations within p-Doped Aromatic Cofacial Arrays Leading to Three-Dimensional (Toroidal) π-Delocalization

Rosokha, Sergiy V., Neretin, Ivan S., Sun, Duoli, Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2006

Language:

english

File:

PDF, 328 KB

english, 2006

29

Intermolecular Electron-Transfer Mechanisms via Quantitative Structures and Ion-Pair Equilibria for Self-Exchange of Anionic (Dinitrobenzenide) Donors

Rosokha, Sergiy V., Lü, Jian-Ming, Newton, Marshall D., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2005

Language:

english

File:

PDF, 201 KB

english, 2005

30

Reversible Interchange of Charge-Transfer versus Electron-Transfer States in Organic Electron Transfer via Cross-Exchanges between Diamagnetic (Donor/Acceptor) Dyads †

Sun, Duoli, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of Physical Chemistry B

Year:

2007

Language:

english

File:

PDF, 356 KB

english, 2007

31

The Question of Aromaticity in Open-Shell Cations and Anions as Ion-Radical Offsprings of Polycyclic Aromatic and Antiaromatic Hydrocarbons

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of Organic Chemistry

Year:

2006

Language:

english

File:

PDF, 204 KB

english, 2006

32

Stable (Long-Bonded) Dimers via the Quantitative Self-Association of Different Cationic, Anionic, and Uncharged π-Radicals: Structures, Energetics, and Optical Transitions

Lü, Jian-Ming, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2003

Language:

english

File:

PDF, 209 KB

english, 2003

33

“Separated” versus “Contact” Ion-Pair Structures in Solution from Their Crystalline States: Dynamic Effects on Dinitrobenzenide as a Mixed-Valence Anion

Lü, Jian-Ming, Rosokha, Sergiy V., Lindeman, Sergey V., Neretin, Ivan S., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2005

Language:

english

File:

PDF, 414 KB

english, 2005

34

Characterizing the Dimerizations of Phenalenyl Radicals by ab Initio Calculations and Spectroscopy: σ-Bond Formation versus Resonance π-Stabilization

Small, David, Rosokha, Sergiy V., Kochi, Jay K., Head-Gordon, Martin

Journal:

Journal of Physical Chemistry A

Year:

2005

Language:

english

File:

PDF, 129 KB

english, 2005

35

Mechanism of Inner-Sphere Electron Transfer via Charge-Transfer (Precursor) Complexes. Redox Energetics of Aromatic Donors with the Nitrosonium Acceptor

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 235 KB

english, 2001

36

Strong electronic coupling in intermolecular (charge-transfer) complexes. Mechanistic relevance to thermal and optical electron transfer from aromatic donors

Rosokha, Sergiy V., Kochi, Jay K.

Journal:

New Journal of Chemistry

Year:

2002

Language:

english

File:

PDF, 211 KB

english, 2002

37

Halogen-bonded assembly of hybrid inorganic/organic 3D-networks from dibromocuprate salts and tetrabromomethane

Rosokha, Sergiy V., Lu, Jianjiang, Rosokha, Tetyana Y., Kochi, Jay K.

Journal:

Chemical Communications

Year:

2007

Language:

english

File:

PDF, 344 KB

english, 2007

38

Trimorphism of a model carcinogen 4-nitroquinoline-N-oxide

Nizhnik, Yakov P., Lu, Jianjiang, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

Year:

2009

Language:

english

File:

PDF, 847 KB

english, 2009

39

Lewis acid effects on donor–acceptor associations and redox reactions: ternary complexes of heteroaromatic N-oxides with boron trifluoride and organic donors

Nizhnik, Yakov P., Lu, Jianjiang, Rosokha, Sergiy V., Kochi, Jay K.

Journal:

New Journal of Chemistry

Year:

2009

Language:

english

File:

PDF, 1.17 MB

english, 2009

40

From charge transfer to electron transfer in halogen-bonded complexes of electrophilic bromocarbons with halide anions

Rosokha, Sergiy V., Traversa, Alfredo

Journal:

Physical Chemistry Chemical Physics

Year:

2015

Language:

english

File:

PDF, 1.99 MB

english, 2015

41

Interplay of Halogen and π–π Charge-Transfer Bondings in Intermolecular Associates of Bromo- or Iododinitrobenzene with Tetramethyl- p -phenylenediamine

Rosokha, Sergiy V., Loboda, Eric A.

Journal:

Journal of Physical Chemistry A

Year:

2015

Language:

english

File:

PDF, 2.27 MB

english, 2015

42

From single-point to three-point halogen bonding between zinc(II) tetrathiocyanate and tetrabromomethane.

Rosokha, Sergiy, Stern, Charlotte L, Vinakos, Michael K.

Journal:

Year:

2015

Language:

english

File:

PDF, 1.19 MB

english, 2015

43

Mechanism and Thermodynamics of Reductive Cleavage of Carbon-Halogen Bonds in the Polybrominated Aliphatic Electrophiles

Rosokha, Sergiy V., Lukacs, Emoke, Ritzert, Jeremy, Wasilewski, Adam

Journal:

Journal of Physical Chemistry A

Year:

2016

Language:

english

File:

PDF, 1.24 MB

english, 2016

44

Anion-π interaction in metal-organic networks formed by metal halides and tetracyanopyrazine

Rosokha, Sergiy V., Kumar, Amar

Journal:

Journal of Molecular Structure

Year:

2017

Language:

english

File:

PDF, 1.39 MB

english, 2017

45

FDHALO17: Electron-transfer reactions of halogenated electrophiles: a different look into the nature of halogen bonding

Rosokha, Sergiy

Journal:

Faraday Discussions

Year:

2017

Language:

english

File:

PDF, 1.92 MB

english, 2017

46

Structural preferences in strong anion-π and halogen-bonded complexes: π- and σ-holes vs frontier orbitals interaction

Grounds, Olivia, Zeller, Matthias, Rosokha, Sergiy

Journal:

New Journal of Chemistry

Year:

2018

Language:

english

File:

PDF, 1.31 MB

english, 2018

47

Continuum of Covalent to Intermolecular Bonding in the Halogen-Bonded Complexes of 1,4-Diazabicyclo[2.2.2]octane with Bromine-Containing Electrophiles

Weinberger, Craig, Hines, Rachel, Zeller, Matthias, Rosokha, Sergiy

Journal:

Chemical Communications

Year:

2018

Language:

english

File:

PDF, 1.69 MB

english, 2018

48

Resolving Halogen vs Hydrogen Bonding Dichotomy in Solutions: Intermolecular Complexes of Trihalomethanes with Halide and Pseudohalide Anions

Watson, Brandon, Grounds, Olivia, Borley, William, Rosokha, Sergiy

Journal:

Physical Chemistry Chemical Physics

Year:

2018

Language:

english

File:

PDF, 858 KB

english, 2018

49

Molecular bases for anesthetic agents: Halothane as halogen and hydrogen bond donor

Resnati, Giuseppe, Nayak, Susanta K., Terraneo, Giancarlo, Piacevoli, Quirino, Bertolotti, Federica, Scilabra, Patrick, Brown, John T., Rosokha, Sergiy

Journal:

Angewandte Chemie International Edition

Year:

2019

Language:

english

File:

PDF, 943 KB

english, 2019

50

Complexes of Diiodine with Heteroaromatic N-oxides:Effects of Halogen-Bond Acceptors in Halogen Bonding

Borley, William, Watson, Brandon, Nizhnik, Yakov P., Zeller, Matthias, Rosokha, Sergiy V.

Journal:

Journal of Physical Chemistry A

Year:

2019

Language:

english

File:

PDF, 1.13 MB

english, 2019